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The chemist Irving Langmuir was a major figure in the development of the theory of thermodynamics. In his book Thermodynamics and Chemistry, Langmuir notes the close relationship between the new subject of thermodynamics and chemistry: "It is well to realize that the present-day science of chemistry was largely the outgrowth of investigation regarding the restricted problem of determinations of the large number of degrees of freedom which are involved in the exchange of heat and of energy between chemical elements. Chemistry is at the moment experiencing a drastic enlargement in the number of its explanatory principles. ">[35] Chemistry and thermodynamics are complementary disciplines, and thermodynamics belongs at the level of physics not at the level of chemistry; chemical thermodynamics must be done by chemists. For a recent presentation of mechanical aspects of thermodynamics, see the textbook by Rosenfeld and Tuckerman[16] and their paper on the hydrodynamics of nonuniform thermoosmosis.[17]
Upon the introduction of thermodynamics more than two centuries ago, the philosophical question of the validity of the axiom of thermodynamic equilibrium, the problem of ontological relations to possible past and future states of a thermodynamic system, entered the formalism of thermodynamics. The task of thermodynamics has always been to explain what happens in thermodynamic systems that are in equilibrium. In the ideas of those inventors of thermodynamics, equilibrium was the absence of motion. In the spirit of that original conception, the very first treatises of thermodynamics dealt with thermodynamic systems at absolute rest on a frictionless surface. The original meaning of equilibrium as a mechanical condition pervaded the theory of thermodynamics at least until the discovery of quantum mechanics. S. Walter[70] has discussed that problem. In the case of thermodynamic equilibrium, then, the modes of being in terms of which thermodynamics was established are taken to be those of absolute rest (see also A.C. Scott, "Friction and thermal engines", International Journal of Engineering Science, 4, 1901, 2-5). d2c66b5586
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